Comparative Evaluation of Emerging Contaminants in Wastewater from Makurdi and Gwer West Local Government Areas, Benue State, Nigeria

Author's Information:

Godsday Idanegbe Usiabulu

World Bank Africa Centre of Excellence, Centre for Oilfield Chemicals Research, University of Port Harcourt, Port Harcourt, Nigeria

Osagioduwa N. Olotu

Department of Public Health and Community Medicine, University of Benin Teaching Hospital, Benin City, Nigeria

Awajiiroijana U. Okpoji*

Department of Pure and Industrial Chemistry, University of Port Harcourt, Choba, Nigeria

Ejikeme E. Onuchukwu

Department of Geological Sciences, Nnamdi Azikiwe University, Awka, Nigeria

Joy C. Obunadike

Department of Agricultural and Vocational Education, Michael Okpara University of Agriculture, Umudike, Nigeria

Emeka C. Izuchukwu

Department of Chemical Pathology, Nnamdi Azikiwe University, Nnewi, Nigeria

Eze L. Osuagwu

Department of Fisheries and Marine Technology, Imo State Polytechnic, Omuma, Nigeria

Nsima A. Akpan

Department of Chemical Sciences, Ritman University, Ikot Ekpene, Nigeria

Chisom A. Amadi

Department of Chemistry, Ignatius Ajuru University of Education, Port Harcourt, Nigeria

Muhammed H. Garuba

Department of Chemistry and Industrial Chemistry, Kwara State University, Malete, Nigeria

John E. Ekpe

Department of Physics, Alex Ekwueme Federal University, Ndufu-Alike, Nigeria

Franklin K. Ugbechie

Department of Chemistry/Biochemistry, Federal Polytechnic Nekede, Nigeria

Sandra U Ekesiobi

School of Public Health, University of Port Harcourt, Choba, Nigeria

Gertrude U. Nwafor

Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

Vol 05 No 05 (2026):Volume 05 Issue 05 May 2026

Page No.: 365-374

Abstract:

Emerging contaminants in wastewater have become major environmental and public health concerns due to their persistence, toxicity, and ecological effects in aquatic environments. This study comparatively evaluated the occurrence and distribution of emerging contaminants in wastewater from Makurdi and Gwer West Local Government Areas of Benue State, Nigeria. A comparative cross-sectional environmental study was conducted using 40 wastewater samples collected from selected drainage systems and wastewater discharge points. Physicochemical parameters, heavy metals, microbial contaminants, and selected emerging contaminants were analysed using standard analytical procedures. Results revealed that wastewater samples from Makurdi recorded higher physicochemical pollution levels compared to Gwer West. Electrical conductivity was 812.4 ± 24.6 µS/cm in Makurdi and 524.7 ± 18.3 µS/cm in Gwer West, while biochemical oxygen demand values were 38.6 ± 3.4 mg/L and 24.1 ± 2.6 mg/L respectively. Caffeine recorded the highest concentration among emerging contaminants with values of 18.42 ± 2.11 µg/L in Makurdi and 9.26 ± 1.34 µg/L in Gwer West. Lead concentrations exceeded WHO permissible limits in both locations, with values of 0.18 ± 0.03 mg/L in Makurdi and 0.07 ± 0.01 mg/L in Gwer West. Microbial analysis showed high total coliform counts of 5.8 × 10⁴ CFU/mL in Makurdi and 2.9 × 10⁴ CFU/mL in Gwer West, alongside the presence of Escherichia coli and Salmonella species. Statistical analysis revealed significant differences in contaminant burden between both locations (p < 0.05). The study demonstrated substantial wastewater contamination, particularly within urban environments, highlighting the need for improved wastewater treatment, environmental monitoring, and pollution control measures.

KeyWords:

Emerging contaminants, wastewater pollution, heavy metals, microbial contamination, urban wastewater, Benue State.

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